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The Molar Enthalpies of Fusion and Vaporisation of Some Substances

Secondary 5

The table below gives an exhaustive list of the molar enthalpy of fusion (ΔHfus) and vaporisation (ΔHvap) of various substances, measured under standard conditions at SATP (standard ambient temperature and pressure), i.e. at 25°C and 101.3 kPa.

Name
ΔHfus
(kJ/mol)
ΔHvap
(kJ/mol)
Name
 
ΔHfus
(kJ/mol)
 
 
ΔHvap
(kJ/mol)
Aluminium (Al) 10.79 294 Krypton (Kr) 1.64 9.08
Silver (Ag) 11.28 258 Magnesium (Mg) 8.48 128
Argon (Ar) 1.18 6.43 Manganese (Mn) 2.91 221
Nitrogen (N2) 0.71 5.57 Mercury (Hg) 2.29 59.1
Beryllium (Be) 7.90 297 Neon (Ne) 0.33 1.71
Boron (B) 50.2 480 Nickel (Ni) 17.04 377.5
Carbon (C) (graphite) 117 - Octasulfur (S8) 1.72 45
Bromine (Br2) 10.57 26.96 Gold (Au) 12.72 324
Chlorine (Cl2) 6.40 20.41 Platinum (Pt) 22.17 469
Fluorine (F2) 0.51 6.62 Lead (Pb) 4.78 179.5
Hydrogen (H2) 0.12 0.90 Radon (Rn) 3.25 18.10
Iodine (I2) 15.52 41.57 Scandium (Sc) 14.1 332.7
Oxygen (O2) 0.44 6.82 Selenium (Se) 6.69 95.48
Chromium (Cr) 21.0 339.5 Silicium (Si) 50.21 359
Cobalt (Co) 16.06 377 White phosphorus (P4) 0.66 12.4
Copper (Cu) 12.93 300.4 Titanium (Ti) 14.15 425
Tin (Sn) 7.17 296.1 Tungsten (W) 52.31 806.7
Iron (Fe) 13.81 340 Uranium (U) 9.14 417.1
Gallium (Ga) 5.58 254 Vanadium (V) 21.5 459
Germanium (Ge) 36.94 334 Xenon (Xe) 2.27 12.57
Helium (He) 0.014 0.08 Zinc (Zn) 7.07 123.6